Dr. Tibor Macko

Adresse Deutsches Kunststoff-Institut
Schlossgartenstr. 6
64289 Darmstadt, Deutschland
Telefon +49-6151-163404
Fax +49-6151-292855

Arbeitsgebiete

  • Flüssigkeitschromatographie von Polyolefinen

Lebenslauf

Geboren 10.09.1955 in Kosice / Tschechoslowakei
1975-1980 Studium der Chemie an der Technischen Universität, Bratislava, Tschechoslowakei
1980 Diplom in analytischer und physikalischer Chemie
1981 Dipl. Ing. im Labor für Flüssigkeitschromatographie im Institut für Polymere an der Slowakischen Akademie der Wissenschaften, Bratislava
1987 Promotion, Thesis: Synthese und Charakterisierung von Silikagelen für die Flüssigkeitschromatographie
1989 Post. Doc. in der Abteilung für Chemie an der Waterloo Universität, Kanada
1992-1995 Institut für Chemie der Kunststoffe, Montanuniversität in Leoben, Österreich
1997-1998 Institut für Experimentelle Veterinärmedizin (Analytisches Labor) in Kosice, Slowakei
2000 Laboratorium für Polyelektrolyte und Biomakromolekülen, Schweizer Institut für Technologie, Lausanne, Schweiz
2001 Institut für Chemie der Kunststoffe, Montanuniversität in Leoben, Österreich
seit 2002 Deutsches Kunststoff-Institut, Darmstadt

Publikationen

  • Macko,.T., Pasch, H., Kazakevich, Y.V., Fadeev, A.Y.:
    Elution behavior of polyethylene in polar mobile phases on a non-polar sorbent
    J. Chromatogr. A, 988 (2003) 69
  • Macko, T., Hunkeler, D.:
    Liquid chromatography under critical and limiting conditions: A survey of experimental systems for synthetic polymers
    Adv. Polym. Sci. 163 (2003) 61
  • Macko, T., Brüll, R., Pasch, H.:
    Applicability of cloud point data in liquid chromatography of polymers and continuous measurement of cloud point for polyolefins in mixed solvents
    Chromatographia 57 (2003) S-39
  • Macko, T., Pasch, H., Denayer, J.F.:
    Adsorption of polyethylene standards from decalin on liquid chromatography column packings
    J. Chromatogr. A, 1002 (2003) 55
  • Macko, T., Denayer, J.F., Pasch, H., Baron, G.V.:
    Adsorption of polyethylene from thermodynamically good solvents on a zeolite stationary phase
    J. Sep. Sci. 26 (2003) 1569
  • Macko, T., Denayer, J.F., Pasch, H., Pan, L., Li, J., Raphael, A.:
    Adsorption of polypropylene and polyethylene on liquid chromatographic column packings
    Chromatographia 59 (2004) 461
  • Macko,T., Adler, M., Pasch, H., Denayer, J. F., Raphael, A.:
    Adsorption of synthetic water-soluble polymers from thermodynamically good solvents in microporous column packings
    J. Liquid. Chromatogr. & Rel. Methods 27 (2004) 1743
  • Macko,T., Pasch, H., Denayer, J.F.:
    Adsorption of polypropylene from dilute solutions on a zeolite column packing
    J. Sep. Sci. 28 (2005) 59
  • Heinz, L.-C., Graef, S., Macko, T., Brüll, R., Balk, S., Keul, H., Pasch, H.:
    Development of High-Temperature Separation Techniques for the Chemical Composition Analysis of Ethylene-Methylmethacrylate Block Copolymers.
    e-polymers (2005) No. 054
  • Wang, X., Rusa, C.C., Hunt, M.A., Tonelli, A.E., Macko, T., Pasch, H:
    Adsorption of polyethylene and polypropylene by zeolites: Inside or outside?br> Macromolecules 38 (2005) 10341
  • Heinz, L. Ch. , Macko, T., Pasch, H., Weiser, M.S., Mülhaupt, R:
    High-temperature liquid chromatography at critical conditions: Separation of polystyrene from blends with polyethylene and ethylene-styrene block copolymers
    Int. J. Polym. Anal. & Characterization 11 (2006) 47
  • Heinz, L.C., Macko, T., Williams, A., O’Donohue, S., Pasch, H.:
    A new system for high-temperature gradient HPLC of polymers.
    The Column (electronic journal), February (2006) 13
  • Macko, T., Pasch, H., Milonjic, S.K., Hiller, W.:
    Adsorption of linear polyethylene and isotactic polypropylene from 1,1,2,2-tetrachloroethane and 1,2,3-trichloropropane on to polar adsorbents.
    Chromatographia 64 (2006) 183
  • Pasch, H., Heinz, L.-C., Macko, T., Williams, A., O’Donohue, S.:
    Hochtemperatur-HPLC von Polyolefinen - Aufbruch zu neuen Horizonten (In German)
    GIT Special - Separation 26, September (2006) 37
  • Macko, T., Pasch, H., Brüll, R.:
    Selective removal of polyethylene or polypropylene from their blends based on difference in their adsorption behaviour
    J. Chromatogr. A, 1115 (2006) 81
  • Hiller, W., Pasch, H., Macko, T., Hofmann, M., Ganz, J., Spraul, M., Braumann, U., Streck, R., Mason, J., Van Damme, F.:
    On-line coupling of high temperature SEC and 1H-NMR for the analysis of polymers
    J. Magnetic Res. 183 (2006) 309
  • Abrecht, A., Brüll, R; Macko, T., Pasch, H.:
    Separation of Ethylene-Vinyl Acetate Copolymers by High-Temperature Gradient Liquid Chromatography,
    Macromolecules 40 (2007) 5545
  • Brüll, R, Geertz, G., Kothe, H.; Macko, T., Rundschuk, M., Wenzel, M., Engelsing, K., Wüst, J., Bastian, M.:
    Analysis of the Influence of Processing Conditions on the Supramolecular Structure and Antioxidant Distribution in PP-Pipes Using Infrared Microscopy
    Macromol. Mater. & Engn. 293 (2008) 400
  • Macko, T., Schulze, U., Brüll, R., Albrecht, A., Pasch, H., Fónagy, T., Häussler, T., Iván, B.:
    Monitoring the Chemical Heterogeneity and the Crystallization Behavior of PP-g-PS Graft Copolymers Using SEC-FTIR and CRYSTAF,
    Macromol. Chem. & Phys. 209 (2008) 404
  • Pasch, H., Heinz, L.C., Macko, T., Hiller, W.:
    High-temperature HPLC and LC-NMR fort he analysis of complex polyolefins
    Pure & Appl. Chem. 80 (2008) 1747
  • Albrecht, A., Macko, T., Brüll, R., Pasch, H.:
    Möglichkeiten der Hochtemperatur-HPLC: Bestimmung der chemischen Zusammensetzungverteilung von Copolymeren aus Ethylen und polaren Comonomeren
    GIT Labor-Fachzeitschrift 03 (2008) 208
  • Macko, T., Pasch, H., Wang, Y.:
    Liquid chromatographic separation of olefin oligomers and its relation to separation of polyolefins – an overview
    Macromol. Symp. 282 (2009) 93
  • Albrecht, A., Brüll, R., Macko, T., Malz, F., Pasch, H.:
    Comparison of high temperature HPLC, CRYSTAF and TREF for the analysis of the chemical composition distribution of ethylene-vinyl acetate copolymers
    Macromol. Chem. & Phys. 210 (2009) 1319
  • Macko, T., Brüll, Brinkmann, C., Pasch, H.:
    Automated monitoring of the establishment of the adsorption equilibrium: Adsorption of polyethylene from 1,2,4-trichlorobenzene onto a zeolite at temperature 140 oC,
    J. Automat. Methods & Managem. in Chem., ID 357026 (2009), 6
  • Pasch, H., Albrecht, A., Brüll, R., Macko, T., Hiller, W.:
    High-temperature interaction chromatography of olefin copolymers,
    Macromol. Symp. 282 (2009) 71
  • Macko, T., Pasch, H.:
    Separation of linear polyethylene from isotactic, atactic and syndiotactic polypropylene by high-temperature adsorption liquid chromatography,
    Macromolecules 42 (2009) 6063
  • Macko, T., Brüll, R., Wang, Y., Thomann, Y.:
    Column high-temperature gradient adsorption liquid chromatography - a novel way of separation for polyolefins,
    The Column (electronic journal), September 4 (2009) 15